I think this Methodist Church is probably one of the most photographed churches around. I did a GOOGLE IMAGES search on it though and I didn't see any shots I liked as much as mine.
[Of course I could be a little biased!] It's taken from the Rich Mountain Road which is a 12 mile unpaved mountain side ride that runs one way from Cades Cove to Townsend, TN.
This shot was hand held with my Olympus O-MD EM1 and a 40-150 F2.8 telephoto all the way out. Settings were F4.5 # 1/800 and ISO 1250 on auto.